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This paper aims to compare the electronic properties of perylene diimide derivatives (DFPDI) and its anion radical (DFPDI.^-k.⁺) thin film by drop-coating of organic molecules on the interdigitated electrodes.

The authors compared the electronic properties of perylene diimide derivatives and its anion radical by drop-coating of organic molecules on interdigitated electrodes. Significantly, the current of perylene diimide derivatives anion radical increased by 2∼3 orders of magnitude compared to perylene diimide derivatives under a bias of 5 V, and the maximal current of anion radical that from tetrahydrofuran solution can reach 3.6 mA. Furthermore, DFPDI.^-k.⁺ thin film showed time-resistance sensitivity for acetic acid. When DFPDI.^-k.⁺ thin film was placed in acetic acid of 3.1 × 105 ppm, the current was decreased 46 times under a bias of 6 V after 8 min.

We developed the new method to prepare ambient stable perylene diimide derivatives anion radical, which shows sensitivity of absorption spectra to acid.

Perylene diimide derivatives anion radical thin film showed time-resistance sensitivity for acetic acid, suggesting potential application of perylene diimide derivatives anion radical as acid sensor.

To explore how the blockchain affects the pricing and financing decisions in a low-carbon platform supply chain.

Considering the dual roles of the e-commerce platform as a seller and an initiator, a typical game-theoretical method is applied to analyze the behavior of supply chain decision-makers and the impact of key variables on equilibriums.

When loan interest rates are symmetric, whether blockchain is used or not, the e-commerce platform financing mode will always produce higher wholesale price and unit carbon emission reduction, while the retail price is the opposite. Higher unit additional income brought by the blockchain can bring higher economic and environmental performances, and the e-commerce platform financing mode is superior to bank financing mode. The application of blockchain may cause the manufacturer to change his/her financing choice. For bank financing, with the increase of loan interest rates, the advantages brought by blockchain will gradually disappear, but this situation will not occur under e-commerce platform financing.

Blockchain is known for its information transparency properties and its ability to enhance user trust. However, the impacts of applying blockchain in a low-carbon platform supply chain with different financing options are not clear. The authors examine the manufacturer's strategic choices for platform financing and bank financing, whether to adopt blockchain, and the impact of these decisions on carbon emissions reduction, consumer surplus and social welfare. The research conclusion can provide reference for the operation and financing decisions of platform supply chain under the carbon reduction target in the digital economy era.